LXXXV.—The constitution of salicin. Synthesis of pentamethyl salicin

Synthesis of acyl derivatives of salicin, salirepin, and arbutin.

The total synthesis of two natural phenolglycosides of the family Salicaceae, namely: populoside and 2-(β-d-glucopyranosyloxy)-5-hydroxy benzyl (3-methoxy-4-hydroxy) cinnamoate and nine not found yet in plants acyl derivatives of phenoglycosides: 2-(β-d-glucopyranosyloxy)-benzylcinnamoate, 2-(β-d-glucopyranosyloxy)-benzyl (4-hydroxy) benzoate, 2-(β-d-glucopyranosyloxy)-benzyl (3-methoxy-4-hydro...

Salicin fermentation by Shigella sonnei.

Shigella species are generally considered to be unable to ferment salicin (Breed, Murray, and Smith, Bergey's Manual of Determinative Bacteriology, The Williams & Wilkins Co., Baltimore, 1957; Kauffmann, Enterobacteriaceae, E. Munksgaard, Copenhagen, 1950; Edwards and Ewing, Identification of Enterobacteriaceae, Burgess Publishing Co., Minneapolis, 1955). Recently, however, Ser6ny (Acta Microbi...

Salicin and treatment of rheumatic diseases.

Salicin, Salicylic Acid and Its Salts

comparative value of this drug with that of other medicinal agents which have already received the sanction of experience, amongst the foremost of which may be mentioned the wet-pack quinine, atropine, aconite, &c., administered subcutaneously. I have tried the last three side by side with salicin, and by thermometric observations during the past two years I have failed to find any superiority ...

Salicin derivatives from Salix glandulosa and their biological activities.

Two new salicin derivatives, saliglandin (1) and 6'-O-(Z)-p-coumaroylsalicin (2), along with fourteen known analogues (3-16) were isolated from the twigs of Salix glandulosa Seemen. The structures of 1-16 were characterized by the use of NMR methods ((1)H and (13)C NMR, (1)H-(1)H COSY, HSQC and HMBC), chemical hydrolysis, and GC/MS. The full NMR data assignment of the known compounds 6, 13, and...